When a material is placed in a magnetic field H, a magnetization M is induced in the material which is related to H by M = κH, where κ is called the volume susceptibility. Because H and M have the same dimensions, κ is dimensionless. A more useful parameter is the molar susceptibility χm, defined by
χm = κVm = κM/ρ
where Vm is the molar volume of the substance, M the molar mass, and ρ the mass density. When the cgs system is used, the customary unit for χm is cm3 mol–1; the corresponding SI base unit is m3 mol–1. Substances with no unpaired electrons are called diamagnetic; they have negative values of χm.
This table gives values of the diamagnetic susceptibility for about 400 common organic compounds. Values are given for both the molar susceptibility χm and the volume susceptibility κ. Note that the tabulated numbers are the negatives of the susceptibility values. Most values of the volume susceptibility κ refer to solids or liquids at room temperature; an asterisk * following the value indicates a liquefied gas. A more extensive table may be found in Ref. 1.
In keeping with customary practice, the molar susceptibility is given here in units appropriate to the cgs system. These values should be multiplied by 4π to obtain values for use in SI equations (where the magnetic field strength H has units of A m–1). Column definitions for the table are as follows.
The CRC Handbook of Chemistry and Physics (HBCP) contains over 700 tables in over 450 documents which may be divided into several pages, all categorised into 17 major subject areas. The search on this page works by searching the content of each page individually, much like any web search. This provides a challenge if you want to search for multiple terms and those terms exist on different pages, or if you use a synonym/abbreviation that does not exist in the document.
We use metadata to avoid some of these issues by including certain keywords invisibly behind each table. Whilst this approach works well in many situations, like any web search it relies in the terms you have entered existing in the document with the same spelling, abbreviation etc.
Since chemical compounds and their properties are immutable, a single centralised database has been created from all chemical compounds throughout HBCP. This database contains every chemical compound and over 20 of the most common physical properties collated from each of the >700 tables. What's more, the properties can be searched numerically, including range searching, and you can even search by drawing a chemical structure. A complete list of every document table in which the compound occurs is listed, and are hyperlinked to the relevant document table.
The 'Search Chemicals' page can be found by clicking the flask icon in the navigation bar at the top of this page. For more detailed information on how to use the chemical search, including adding properties, saving searches, exporting search results and more, click the help icon in to top right of this page, next to the welcome login message.
Below is an example of a chemical entry, showing its structure, physical properties and document tables in which it appears.
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