Section: 6 | Sublimation Pressure of Solids |

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SUBLIMATION PRESSURE OF SOLIDS

This table gives the sublimation (vapor) pressure of some representative solids as a function of temperature. Entries include simple inorganic and organic substances in their solid phase below room temperature, as well as polycyclic organic compounds which show measurable sublimation pressure only at elevated temperatures. Substances are listed by molecular formula in the Hill order, with inorganic compounds preceding compounds containing carbon. Each substance has two rows of data. The top row has temperatures; the bottom row has the values of the sublimation pressure at that temperature.

Values marked by * represent the solid–liquid–gas triple point. Note that some pressure values are in pascals (Pa), and others are in kilopascals (kPa).

References

Lide, D. R. and Kehiaian, H. V., CRC Handbook of Thermophysical and Thermochemical Data, CRC Press, Boca Raton, FL, 1994.
TRC Thermodynamic Tables, Thermodynamic Research Center, Texas A&M University, College Station, TX.
Oja, V. and Suuberg, E. M., J. Chem. Eng. Data 43, 486, 1998. [https://doi.org/10.1021/je970222l]
Guder, C., and Wagner, W., J. Phys. Chem. Ref. Data 38, 33, 2009. [sulfur hexafluoride] [https://doi.org/10.1063/1.3037344]
Lemmon, E. W. and Span, R., J. Chem. Eng. Data 51 785, 2006. [krypton, xenon] [https://doi.org/10.1021/je050186n]
Setzmann, U., and Wagner, W., J. Phys. Chem. Ref. Data 20, 1061, 1991. [methane] [https://doi.org/10.1063/1.555898]
Span, R., and Wagner, W., J. Phys. Chem. Ref. Data 25, 1509, 1996. [carbon dioxide] [https://doi.org/10.1063/1.555991]
Katti, R. S., Jacobsen, R. T, Stewart, R. B., and Jahangiri, M., Adv. Cryo. Eng. 31, 1189, 1986. [neon] [https://doi.org/10.1007/978-1-4613-2213-9_132]
Span, R., Lemmon, E. W., Jacobsen, R. T, Wagner, W., and Yokozeki, A., J. Phys. Chem. Ref. Data 29, 1361, 2000. [nitrogen] [https://doi.org/10.1063/1.1349047]

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Sublimation Pressure of Solids as a Function of Temperature

Name	Mol. form.
Continued on next page...
Inorganic
Argon	Ar	T/K	55	60	65	70	75	80	83.81
Argon	Ar	p/kPa	0.2	0.8	2.8	7.7	18.7	40.7	68.89
Hydrogen bromide	BrH	T/K	135	140	150	160	170	180	185.1
Hydrogen bromide	BrH	p/kPa	0.1	0.3	1.1	3.3	8.7	20.1	27.4
Bromine	Br₂	T/K	170	180	190	200	210	220	230	240
Bromine	Br₂	p/Pa	0.069	0.416	2.04	8.45	30.3	96.0	273	710
Hydrogen chloride	ClH	T/K	120	130	140	150	155	159.0
Hydrogen chloride	ClH	p/kPa	0.1	0.5	1.9	5.8	9.5	13.5
Chlorine	Cl₂	T/K	120	130	140	150	160	172.17
Chlorine	Cl₂	p/Pa	0.144	1.52	11.2	63.1	283	1392
Silicon tetrafluoride	F₄Si	T/K	130	140	150	160	170	175	180	186.3
Silicon tetrafluoride	F₄Si	p/kPa	0.2	0.9	3.9	14.0	43.8	74.2	122.4	220.8
Sulfur hexafluoride	F₆S	T/K	150	165	180	190	200	210	220	223.554
Sulfur hexafluoride	F₆S	p/kPa	0.4566	2.596	10.94	25.07	52.71	103	189	232.7
Hydrogen iodide	HI	T/K	160	170	180	190	200	210	220	222.35
Hydrogen iodide	HI	p/kPa	0.2	0.8	2.2	5.3	11.7	23.6	44.1	49.3
Water	H₂O	T/K	190	210	225	240	250	260	270	273.16
Water	H₂O	p/Pa	0.032	0.702	4.942	27.28	76.04	195.8	470.1	611.655
Hydrogen sulfide	H₂S	T/K	140	150	160	165	170	175	180	187.55

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SUBLIMATION PRESSURE OF SOLIDS

References

Sublimation Pressure of Solids as a Function of Temperature

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