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Section: 6 | Thermal Properties of Mercury |
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John R. Rumble, ed., CRC Handbook of Chemistry and Physics, 103rd Edition (Internet Version 2022), CRC Press/Taylor & Francis, Boca Raton, FL.
If a specific table is cited, use the format: "Physical Constants of Organic Compounds," in CRC Handbook of Chemistry and Physics, 103rd Edition (Internet Version 2022), John R. Rumble, ed., CRC Press/Taylor & Francis, Boca Raton, FL.

THERMAL PROPERTIES OF MERCURY

Lev R. Fokin

This table has thermal properties for solid, liquid, and gaseous mercury over a range of temperatures. Column definitions are as follows.

Column heading Definition
t Temperature, in °C
Cp(s) Molar heat capacity of solid mercury, in units J mol-1 K-1 (Refs. 1 and 2)
Cp(l) Molar heat capacity of liquid mercury, in units J mol-1 K-1 (Ref. 3)
Cp(g) Molar heat capacity of mercury gas, in units J mol-1 K-1 (Ref. 3)
σT(l) Cubic thermal expansion of liquid mercury, in units 104 × K-1 (Ref. 4)
κT(l)(1 bar) Isothermal compressibility coefficient of liquid mercury at 1 bar, in units 106 × bar-1 (Ref. 4)
κT(l)(1 kbar) Isothermal compressibility coefficient of liquid mercury at 1 kbar, in units 106 × bar-1 (Ref. 4)
u(l) Speed of sound in liquid mercury, in units m s-1 (Ref. 4)

The last three properties are defined as follows (v is the specific volume and ρ the density):

α=1v(∂v∂T)p  κT=−1v(∂v∂P)T  u2=(∂P∂ρ)s  ρ=v−1

References

  1. Busey, R. H., and Giaque, W. F., J. Am. Chem. Soc., 75, 806, 1953. [https://doi.org/10.1021/ja01100a014]
  2. Amitin, Lebedeva, and Paukov, Rus. J. Phys. Chem., 2666, 1979.
  3. Douglas, T. B., Ball, A. T., and Ginnings, D. C., J. Res. Natl. Bur. Stands., 46, 334, 1951. [https://doi.org/10.6028/jres.046.038]
  4. Vukalovich, M. P., et al., Thermophysical Properties of Mercury, Moscow Standard Press, 1971.
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Thermal Properties of Solid, Liquid, and Gaseous Mercury



t/°CCp(s)/J mol-1 K-1Cp(l)/J mol-1 K-1Cp(g)/J mol-1 K-1104 × α(l)/K-1κT(l)(1 bar)/106 × bar-1κT(l)(1 kbar)/106 × bar-1u(l)/m s-1
Continued on next page...
-268.99a0.99
-268.99b0.9720.786
-268.151.620.786
-263.154.620.786
-258.157.620.786
-253.1510.3320.786
-248.1512.7420.786
-243.1514.7820.786
-233.1517.9020.786
-223.1519.9420.786
-213.1521.4020.786
-203.1522.4220.786
-193.1523.1620.786
-183.1523.7620.786
-173.1524.2420.786
-153.1525.0020.786
-133.1525.6120.786
-113.1526.1520.786
-93.1526.6920.786

  • aSuperconducting state
  • bNormal state


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