Light amplification by stimulated emission of radiation was first demonstrated by Maiman in 1960, the result of a population inversion produced between energy levels of chromium ions in a ruby crystal when irradiated with a xenon flashlamp. Since then population inversions and coherent emission have been generated in literally thousands of substances (neutral and ionized gases, liquids, and solids) using a variety of incoherent excitation techniques (optical pumping, electrical discharges, gas-dynamic flow, electron-beams, chemical reactions, nuclear decay).
The extrema of laser output parameters that have been demonstrated to date and the laser media used are summarized in Table 1. Note that the extreme power and energy parameters listed in this table were attained with laser systems rather than with simple laser oscillators.
Laser sources are commonly classified in terms of the state-of- matter of the active medium: gas, liquid, and solid. Each of these classes is further subdivided into one or more types as shown in Table 2. A well-known representative example of each type of laser is also given in Table 2 together with its nominal operation wavelength and the methods by which it is pumped.
The various lasers together cover a wide spectral range from the far ultraviolet to the far infrared. The particular wavelength of emission (usually a narrow line) is presented for some six dozen lasers in Figures 1A and 1B.
By suitably designing the excitation source and/or by controlling the laser resonator structure, laser systems can provide continuous or pulsed radiation as shown in Table 3.
Besides the method of excitation and the temporal behavior of a laser, there are many other parameters that characterize its operation and efficiency, as shown in Tables 4 and 5.
Although many lasers only emit in one or more narrow spectral “lines,” an increasing number of lasers can be tuned by changing the composition or the pressure of the medium, or by varying the wavelength of the pump bands. The spectral regions in which these tunable lasers operate are presented in Figure 2.
Parameter | Value | Laser medium |
Peak power | 1 × 1014 W (collimated) | Nd:glass |
Peak power density | 1018 W/cm2 (focused) | Nd:glass |
Pulse energy | >105 J | CO2, Nd:glass |
Average power | 105 W | CO2 |
Pulse duration | 3 × 10-15 s continuous wave (cw) | Rh6G dye; various gases, liquids, solids |
Wavelength | 60 nm ↔ 385 µm | Many required |
Efficiency (nonlaser pumped) | 70% | CO |
Beam quality | Diffraction limited | Various gases, liquids, solids |
Spectral linewidth | 20 Hz (for 10-1 s) | Neon-helium |
Spatial coherence | 10 m | Ruby |
Type (characteristic) | Representative example | Nominal operating wavelength (nm) | Method(s) of excitation |
Gas | |||
Atom, neutral (electronic transition) | Neon-Helium (Ne-He) | 633 | Glow discharge |
Atom, ionic (electronic transition) | Argon (Ar+) | 488 | Arc discharge |
Molecule, neutral (electronic transition) | Krypton fluoride (KrF) | 248 | Glow discharge; e-beam |
Molecule, neutral (vibrational transition) | Carbon dioxide (CO2) | 10600 | Glow discharge; gasdynamic flow |
Molecule, neutral (rotational transition) | Methyl fluoride (CH3F) | 496000 | Laser pumping |
Molecule, ionic (electronic transition) | Nitrogen ion (N2+) | 420 | E-beam |
Liquid | |||
Organic solvent (dye-chromophore) | Rhodamine dye (Rh6G) | 580–610 | Flashlamp; laser pumping |
Organic solvent (rare earth chelate) | Europium:TTF | 612 | Flashlamp |
Inorganic solvent (trivalent rare earth ion) | Neodymium:POCl4 | 1060 | Flashlamp |
Solid | |||
Insulator, crystal (impurity) | Neodymium:YAG | 1064 | Flashlamp, arc lamp |
Insulator, crystal (stoichiometric) | Neodymium:UP(NdP5O14) | 1052 | Flashlamp |
Insulator, crystal (color center) | F2–:LiF | 1120 | Laser pumping |
Insulator, amorphous (impurity) | Neodymium:glass | 1061 | Flashlamp |
Semiconductor (p-n junction) | GaAs | 820 | Injection current |
Semiconductor (electron-hole plasma) | GaAs | 890 | E- beam, laser pumping |
FIGURE 1A. Wavelengths of lasers operating in the 120 to 1200 nm spectral region.
FIGURE 1B. Wavelength of lasers operating in the 1300 to 12,000 nm spectral region.
Form | Technique | Pulse width range(s) |
Continuous wave | Excitation is continuous; resonator Q is held constant at some moderate value | ∞ |
Pulsed | Excitation is pulsed; resonator Q is held constant at some moderate value | 10-8 – 10-3 |
Q-Switched | Excitation is continuous or pulsed; resonator Q is switched from a very low value to a moderate value | 10-8 – 10-6 |
Cavity dumped | Excitation is continuous or pulsed; resonator Q is switched from a very high value to a low value | 10-7 – 10-5 |
Mode locked | Excitation is continuous or pulsed; phase or loss of the resonator modes is modulated at a rate related to the resonator transit time | 10-12 – 10-9 |
Parameter | Unit | Ne-He (gas) | Ar+ (gas) | CO2 (gas) | Rhodamine 6G dye (liquid) | Nd:YAG (solid) | GaAs (solid) |
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Excitation method | DC discharge | DC discharge | DC discharge | Ar+ laser pump | Krypton arc lamp | DC injection | |
Gain medium composition | Neon:helium | Argon | CO2:N2:He | Rh 6G:H2O | Nd:YAG | p:n:GaAs | |
Gain medium density | Torr | 0.1:1.0 | 0.4 | 0.4:0.8:5.0 | |||
ions/cm3 | 2(18):2(22) | 1.5(20):2(22) | 2(19):3(18):3(22) | ||||
Wavelength | nm | 633 | 488 | 10600 | 590 | 1064 | 810 |
Laser cross-section | cm-2 | 3(-13) | 1.6(-12) | 1.5(-16) | 1.8(-16) | 7(-19) | ~6(-15) |
Radiative lifetime (upper level) | s | ~1(-7) | 7.5(-9) | 4(-3) | 6.5(-9) | 2.6(-4) | ~1(-9) |
Decay lifetime (upper level) | s | ~1(-7) | ~5.0(-9) | ~4(-3) | 6.0(-9) | 2.3(-4) | ~1(-9) |
Gain bandwidth | nm | 2(-3) | 5(-3) | 1.6(-2) | 80 | 0.5 | 10 |
Type, gain saturation | Inhomogeneous | Inhomogeneous | Homogeneous | Homogeneous | Homogeneous | Homogeneous | |
Homogeneous saturation flux | W cm-2 | ~20 | 3(5) | 2.3(3) | ~2(4) | ||
Decay lifetime (lower level) | s | ~1(-8) | ~4(-10) | ~5(-6) | <1(-12) | <1(-7) | <1(-12) |
Inversion density | cm-3 | ~1(9) | 2(10) | 2(15) | 2(16) | 6(16) | 1(16) |
Small signal gain coefficient | cm-1 | ~1(-3) | ~3(-2) | 1(-2) | 4 | 5(-2) | 40 |
Pump power density | W cm-3 | 3 | 900 | 0.15 | 1(6) | 150 | 7(7) |
Output power density | W cm-3 | 2.6(-3) | ~1 | 2(-2) | 3(5) | 95 | 5(6) |
Laser size (diameter:length) | cm:cm | 0.5:100 | 0.3:100 | 5.0:600 | 1(-3):0.3 | 0.6:10 | 5(-4):7(-3);2(-2)a |
Excitation current/voltage | A/V | 3(-2):2(3) | 30:300 | 0.1:1.5(4) | 90:125 | 1.0/1.7 | |
Excitation current density | A cm-2 | 0.15 | 600 | 6(-3) | 140 | 4.5(3) |
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