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Section: 15 | Miscibility of Organic Solvents |
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One or more tables in this document differ to those in the book. This is due to space restrictions in the book.
Summary of table differences
The table 'TABLE 1. Miscibility of Organic Solvents - Group A' has one or more different columns to those in the book version.
The table 'TABLE 2. Miscibility of Organic Solvents - Group B' has one or more different columns to those in the book version.
The table 'TABLE 3. Miscibility of Organic Solvents - Group C' has one or more different columns to those in the book version.
How to Cite this Reference
The recommended form of citation is:
John R. Rumble, ed., CRC Handbook of Chemistry and Physics, 103rd Edition (Internet Version 2022), CRC Press/Taylor & Francis, Boca Raton, FL.
If a specific table is cited, use the format: "Physical Constants of Organic Compounds," in CRC Handbook of Chemistry and Physics, 103rd Edition (Internet Version 2022), John R. Rumble, ed., CRC Press/Taylor & Francis, Boca Raton, FL.

MISCIBILITY OF ORGANIC SOLVENTS

The tables below give qualitative information on the miscibility of pairs of organic liquids. Two liquids are considered miscible if mixing equal volumes produces a single liquid phase. If two phases separate, they are considered immiscible. An entry of partially misc. indicates two phases whose volumes differ appreciably, suggesting a partial miscibility of the compo­nents. The entry reaction indicates a chemical reaction between the compo­nents. All data refer to room temperature.

The initial column is repeated in all three tables. The second liquids, given as column headings, are divided into three groups as follows. In some instances, synonyms for these compounds (as given in parentheses below an entry) are used as row labels.

Table 1 Table 2 Table 3
Group A Group B Group C
Acetone Diethyl ether Glycerol
Benzaldehyde N,N-Dimethylaniline

Methyl isopropyl ketone

(3-Methyl-2-butanone)
Benzene Dipentylamine Nitromethane
Butyl acetate

Ethyl alcohol

(Ethanol)

 1-Octanol

Butyl alcohol

(1-Butanol)

Ethylene glycol

(1,2-Ethanediol)

 1,3-Propanediol

Carbon tetrachloride

(Tetrachloromethane)

Ethylene glycol monoethyl ether

(2-Ethoxyethanol)

 Pyridine
2-Chloroethanol Formamide

Triethylenetetramine

(N,N-Bis(2-aminoethylene)-1,2-ethanediamine)

Chloroform

(Trichloromethane)

 Furfuryl alcohol Triethyl phosphate
o-Cresol

References

  1. Drury, J. S., Ind. Eng. Chem. 44, 2744, 1959. [https://doi.org/10.1021/ie50515a065]
  2. Jackson, W. M., and Drury, J. S., Ind. Eng. Chem. 51, 1491, 1959. [https://doi.org/10.1021/ie50600a039]
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TABLE 1. Miscibility of Organic Solvents - Group A



NameSynonymMol. form.FormulaCAS NumMol. wt.AcetoneBenzaldehydeBenzeneButyl acetateButyl alcohol
(1-Butanol)		Carbon tetrachloride
(Tetrachloromethane)		2-ChloroethanolChloroform
(Trichloromethane)		o-Cresol
Continued on next page...
Acetone2-PropanoneC3H6O(CH3)2CO67-64-158.079-misciblemisciblemisciblemisciblemisciblemisciblemiscible
2-Amino-2-methyl-1-propanolAMPC4H11NO124-68-589.136misciblemisciblemisciblemisciblemisciblemiscible
BenzaldehydeBenzenecarboxaldehydeC7H6OC6H5CHO100-52-7106.122miscible-misciblemisciblemisciblemiscible
Benzene[6]AnnuleneC6H6C6H671-43-278.112misciblemiscible-misciblemisciblemisciblemisciblemiscible
BenzenemethanethiolThiobenzyl alcoholC7H8S100-53-8124.204misciblemisciblemisciblemiscible
BenzonitrilePhenyl cyanideC7H5NC6H5CN100-47-0103.122misciblemisciblemisciblemiscible
BenzothiazoleBenzosulfonazoleC7H5NS95-16-9135.187misciblemisciblemisciblemiscible
Benzyl alcoholBenzenemethanolC7H8OC7H8O100-51-6108.138misciblemisciblemisciblemisciblemisciblemiscible
Bis(2-aminoethyl)amineDiethylenetriamineC4H13N3C4H13N3111-40-0103.166misciblemisciblereactionmiscible
N,N'-Bis(2-aminoethyl)-1,2-ethanediamineTriethylenetetramineC6H18N4112-24-3146.234misciblemisciblemisciblemiscible
2-Bromoethyl acetateC4H7BrO2927-68-4167.002misciblepartially misc.miscible
1,3-Butanediol1,3-Butylene glycolC4H10O2107-88-090.121miscibleimmisciblemisciblemiscible
2,3-ButanediolC4H10O26982-25-890.121misciblepartially misc.misciblemiscible
1-ButanolButyl alcoholC4H10OC4H9OH71-36-374.121misciblemisciblemisciblemiscible-miscible
2-ButoxyethanolEthylene glycol monobutyl etherC6H14O2C6H14O2111-76-2118.174misciblemisciblemisciblemiscible
Butyl acetateC6H12O2C6H12O2123-86-4116.158misciblemisciblemiscible-misciblemiscible
2-ChloroethanolEthylene chlorohydrinC2H5ClOC2H5ClO107-07-380.513misciblemiscible-miscible
3-Chloro-1,2-propanediolα-ChlorohydrinC3H7ClO296-24-2110.540miscibleimmisciblemisciblemiscible
trans-Cinnamaldehyde3-Phenyl-2-propenal, (E)-C9H8O14371-10-9132.159misciblemisciblemisciblemiscible


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