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Section: 15 | Miscibility of Organic Solvents |
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John R. Rumble, ed., CRC Handbook of Chemistry and Physics, 102nd Edition (Internet Version 2021), CRC Press/Taylor & Francis, Boca Raton, FL.
If a specific table is cited, use the format: "Physical Constants of Organic Compounds," in CRC Handbook of Chemistry and Physics, 102nd Edition (Internet Version 2021), John R. Rumble, ed., CRC Press/Taylor & Francis, Boca Raton, FL.

MISCIBILITY OF ORGANIC SOLVENTS

The chart below gives qualitative information on the miscibility of pairs of organic liquids. Two liquids are considered miscible if mixing equal volumes produces a single liquid phase. If two phases separate, they are considered immiscible. An entry of partially misc. indicates two phases whose volumes differ appreciably, suggesting a partial miscibility of the compo­nents. The entry reaction indicates a chemical reaction between the compo­nents. All data refer to room temperature.

References

  1. Drury, J. S., Ind. Eng. Chem. 44, 2744, 1959. [https://doi.org/10.1021/ie50515a065]
  2. Jackson, W. M., and Drury, J. S., Ind. Eng. Chem. 51, 1491, 1959. [https://doi.org/10.1021/ie50600a039]
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Miscibility of Organic Solvents



NameSynonymMol. Form.FormulaCAS Reg. No.Mol. Wt.AcetoneBenzaldehydeBenzeneButyl acetateButyl alcoholCarbon tetrachloride2-ChloroethanolChloroformo-CresolDiethyl etherN,N-DimethylanilineDipentylamineEthyl alcoholEthylene glycolEthylene glycol monoethyl etherFormamideFurfuryl alcoholGlycerolMethyl isopropyl ketoneNitromethane1-Octanol1,3-PropanediolPyridineTriethylenetetramineTriethyl phosphate
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Acetone2-PropanoneC3H6O(CH3)2CO67-64-158.079-misciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemiscibleimmisciblemisciblemisciblemisciblemisciblemisciblemisciblemiscible
2-Amino-2-methyl-1-propanolAMPC4H11NO124-68-589.136misciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemiscible
BenzaldehydeBenzenecarboxaldehydeC7H6OC6H5CHO100-52-7106.122miscible-misciblemisciblemisciblemisciblemisciblemisciblemisciblepartially misc.misciblemisciblepartially misc.misciblemisciblemisciblemiscible
Benzene[6]AnnuleneC6H6C6H671-43-278.112misciblemiscible-misciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemiscibleimmisciblemiscibleimmisciblemiscibleimmisciblemiscibleimmisciblemiscibleimmisciblemisciblemisciblemiscible
BenzenemethanethiolThiobenzyl alcoholC7H8S100-53-8124.204misciblemisciblemisciblemisciblemisciblemisciblemiscibleimmiscibleimmisciblemiscibleimmiscibleimmisciblemiscible
BenzonitrilePhenyl cyanideC7H5NC6H5CN100-47-0103.122misciblemisciblemisciblemisciblemisciblemisciblemiscibleimmiscibleimmisciblemiscibleimmiscibleimmisciblemiscible
BenzothiazoleBenzosulfonazoleC7H5NS95-16-9135.187misciblemisciblemisciblemisciblemisciblemisciblemisciblemiscibleimmisciblemiscibleimmisciblemisciblemiscible
Benzyl alcoholBenzenemethanolC7H8OC7H8O100-51-6108.138misciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemiscible
Bis(2-aminoethyl)amineDiethylenetriamineC4H13N3C4H13N3111-40-0103.166misciblemisciblereactionmiscibleimmisciblemisciblemisciblemisciblemisciblereactionmisciblemiscible
N,N'-Bis(2-aminoethyl)-1,2-ethanediamineTriethylenetetramineC6H18N4112-24-3146.234misciblemisciblemisciblemisciblemiscibleimmisciblemisciblemisciblemisciblemisciblereactionmiscible-miscible
2-Bromoethyl acetateC4H7BrO2927-68-4167.002misciblepartially misc.misciblereactionmisciblemisciblereaction
1,3-Butanediol1,3-Butylene glycolC4H10O2107-88-090.121miscibleimmisciblemisciblemisciblepartially misc.misciblemisciblemisciblemisciblemiscible
2,3-ButanediolC4H10O26982-25-890.121misciblepartially misc.misciblemisciblemisciblemisciblemisciblemisciblemisciblemiscible
1-ButanolButyl alcoholC4H10OC4H9OH71-36-374.121misciblemisciblemisciblemiscible-misciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemiscible
2-ButoxyethanolEthylene glycol monobutyl etherC6H14O2C6H14O2111-76-2118.174misciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemisciblemiscible
Butyl acetateC6H12O2C6H12O2123-86-4116.158misciblemisciblemiscible-misciblemisciblemisciblemisciblemisciblepartially misc.immisciblemiscibleimmisciblemisciblemisciblepartially misc.miscible
2-ChloroethanolEthylene chlorohydrinC2H5ClOC2H5ClO107-07-380.513misciblemiscible-misciblemisciblemisciblemisciblemisciblemisciblemiscible
3-Chloro-1,2-propanediolα-ChlorohydrinC3H7ClO296-24-2110.540miscibleimmisciblemisciblemisciblemisciblereactionmisciblemisciblemisciblereaction
trans-Cinnamaldehyde3-Phenyl-2-propenal, (E)-C9H8O14371-10-9132.159misciblemisciblemisciblemisciblemisciblemiscibleimmisciblemiscibleimmisciblemiscibleimmisciblereactionmiscible


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