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Section: 16 | Flammability Hazards of Common Solvents |
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John R. Rumble, ed., CRC Handbook of Chemistry and Physics, 103rd Edition (Internet Version 2022), CRC Press/Taylor & Francis, Boca Raton, FL.
If a specific table is cited, use the format: "Physical Constants of Organic Compounds," in CRC Handbook of Chemistry and Physics, 103rd Edition (Internet Version 2022), John R. Rumble, ed., CRC Press/Taylor & Francis, Boca Raton, FL.

FLAMMABILITY HAZARDS OF COMMON SOLVENTS

Thomas J. Bruno and Paris D. N. Svoronos

Table 1 lists relevant data regarding the flammability of common organic solvents. Refs. 1-2 contain additional information. See “Flammability of Chemical Substances” in this section for a more extensive list of compounds.

Column definitions for Table 1 are as follows.

Column heading Definition
Name Name of organic solvent; solvents are listed alphabetically by name
Mol. form. Molecular formula of organic solvent
ρ Density, in g cm-3, at temperature in °C as indicated by foonote
tbp Normal boiling point temperature, in °C; expl = explosive at the indicated temperature
tflp Flash point temperature, in °C
taip Autoignition point temperature, in °C
How to extinguish fires Recommended method for extinguishing a fire of this solvent; codes for entries in the last column are given in Table 2

.

References

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TABLE 1. Flammability Hazards of Common Solvents



NameSynonymMol. form.ρ/g cm-3tbp/°Ctflp/°Ctaip/°CHow to extinguish fires
Continued on next page...
AcetaldehydeEthanalCH3CHO0.78341820.8-39175a,b,c
Acetone2-Propanone(CH3)2CO0.79022056.08-20465a,b
AcetonitrileMethyl cyanideCH3CN0.78252081.66524a,c,d
Acrolein2-PropenalCH2=CHCHO0.8402052.3-26220a,b,c
AcrylonitrilePropenenitrileCH2=CHCN0.80072577.20481a,c,d
Allylamine2-Propen-1-amineCH2=CHCH2NH20.7582054-29374a,b
AnilineBenzenamineC6H5NH21.025020184.170615a,b,c; use masks
AnisoleMethoxybenzeneC7H8O0.994020153.652475a,b,c
BenzaldehydeBenzenecarboxaldehydeC6H5CHO1.040125178.763192a,b,c
Benzene[6]AnnuleneC6H60.87882080.08-11498a,b,c
ButanalButyraldehydeC4H8O0.80162074.8-22218a,b,c
2,3-ButanedioneDiacetylC4H6O20.98081887.527a,b,c
1-ButanolButyl alcoholC4H9OH0.814820117.637343a,b,c
2-ButanoneMethyl ethyl ketoneC4H8O0.79992579.6-9404a,b,c
2-Butanone peroxideMethyl ethyl ketone peroxideC8H16O463 expla,b
trans-2-Butenaltrans-CrotonaldehydeC4H6O0.851620102.213232a,b,c
tert-Butyl peroxyacetatetert-Butyl peracetateC6H12O3>1.0expl<27a,b,c
tert-Butyl peroxybenzoateBenzoyl tert-butyl peroxideC11H14O31.02125118 expl>888b,c
Carbon disulfideCarbon bisulfideCS21.26322046.2-3090b,d; use masks

  • aMixture of C5 to C10 hydrocarbons, mostly aliphatic (C5 to C6 for petroleum ether).
  • bAqueous solution.
  • cVaries widely with manufacturer.


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